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The fourth quantum number is the spin quantum number, s.There are only two values for s, +½ and -½.These are also referred to as 'spin up' and 'spin down'. This number is used to explain the behavior of individual electrons as if they were spinning in a clockwise or counterclockwise.
Quantum numbers arise naturally from the mathematics used to describe the possible states of an electron in an atom. The four quantum numbers, the principal quantum number (n), the angular momentum quantum number (?), the magnetic quantum number (m?), and the spin quantum number (ms) have strict rules which govern the possible values.
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The first quantum number, n, is called the principal quantum number, the second quantum number, ℓ, is called the azimuthal quantum number, and the third quantum number, m l, is called the magnetic quantum number. Together these three quantum numbers define the energy state and orbital of an electron, but we'll talk more about exactly what.
The spin projection quantum number (m s) describes the spin (intrinsic angular momentum) of the electron within that orbital, and gives the projection of the spin angular momentum S along the specified axis: S z = m s ħ. In general, the values of m s range from −s to s, where s is the spin quantum number, an intrinsic property of particles:
The Magnetic Quantum Number. We have addresses to tell our friends where we live. In the world of subatomic particles, electrons also have an 'address' that gives us an idea where they are located.

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